Aqua(2,2′-bipyridine-κ2 N,N′){(E)-[(5-chloro-2-oxidobenzylidene)amino-κ2 N,O]methanesulfonato-κO}zinc
نویسندگان
چکیده
In the title compound, [Zn(C(8)H(6)ClNO(4)S)(C(10)H(8)N(2))(H(2)O)], the Zn(II) atom is six-coordinated by two O atoms and one N atom from a tridentate Schiff base ligand and two N atoms from a chelating 2,2'-bipyridine ligand and one water mol-ecule, forming a slightly distorted octa-hedral geometry. In the crystal, O-H⋯O hydrogen bonds link pairs of complex mol-ecules into dimers. An intra-molecular O-H⋯O hydrogen bond is also present.
منابع مشابه
catena-Poly[[[aqua(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ2 O 2:O 3] [[(4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)zinc]-μ-3-chlorobenzene-1,2-dicaboxylato-κ2 O 2:O 3]]
In the title compound, {[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))(H(2)O)]·[Zn(C(8)H(3)ClO(4))(C(12)H(12)N(2))]}(n), one Zn(2+) ion is five-coordin-ated by two O atoms from two different 3-chloro-benzene-1,2-dicarboxyl-ate ligands, one O atom from a water mol-ecule and two N atoms from a 4,4'-dimethyl-2,2'-bipyridine ligand, while the second Zn(2+) ion is four-coordinated by two O atoms from two diffe...
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In the crystal structure of the title compound, [Sn(CH(3))(2)(C(9)H(8)N(2)O(3))(C(10)H(8)N(2))], the Sn atom exhibits a penta-gonal bipyramidal coordination geometry defined by two C, three N and two O atoms. The bond distances for Sn-C, Sn-N and Sn-O are in the ranges 2.097 (3)-2.098 (3), 2.298 (2)-2.623 (2) and 2.157 (2)-2.266 (2) Å, respectively. The mol-ecular structure of the monomeric com...
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